An overview of current status of carbon dioxide capture and storage technologies

AbstractGlobal warming and climate change concerns have triggered global efforts to reduce the concentration of atmospheric carbon dioxide (CO2). Carbon dioxide capture and storage (CCS) is considered a crucial strategy for meeting CO2 emission reduction targets. In this paper, various aspects of CCS are reviewed and discussed including the state of the art technologies for CO2 capture, separation, transport, storage, leakage, monitoring, and life cycle analysis. The selection of specific CO2 capture technology heavily depends on the type of CO2 generating plant and fuel used. Among those CO2 separation processes, absorption is the most mature and commonly adopted due to its higher efficiency and lower cost. Pipeline is considered to be the most viable solution for large volume of CO2 transport. Among those geological formations for CO2 storage, enhanced oil recovery is mature and has been practiced for many years but its economical viability for anthropogenic sources needs to be demonstrated. There are growing interests in CO2 storage in saline aquifers due to their enormous potential storage capacity and several projects are in the pipeline for demonstration of its viability. There are multiple hurdles to CCS deployment including the absence of a clear business case for CCS investment and the absence of robust economic incentives to support the additional high capital and operating costs of the whole CCS process

Monitoring techniques of a natural analogue for sub-seabed CO2 leakages

Carbon dioxide sequestration in sub-seafloor aims to store CO2 inside geological trapping structures below the seafloor. However there are concerns related to the possibility of leakage from the storage sites and potential consequences on the marine environment. In order to develop safe and reliable methods for CO2 monitoring, field studies were conducted in a natural analogue–an area where there is a natural release of CO2 from the seafloor. Due to the very high volume of gas emitted, this natural analogue could be considered as the worst-case scenario for a possible leakage from a sub-seabed storage site. Sampling procedures for free and dissolved gas and measuring techniques of the main physical and chemical parameters were developed for use both from the surface and directly underwater by scientific scuba divers. The first results of the research indicate that high levels of CO2 released in the marine realm strongly affect the local environmental conditions with a generalized acidification of the seawater. The experience gained in this study allows further development of a more accurate and suitable monitoring suite that will integrate sensors for measuring pH, dissolved CO2, and eventually, acoustic systems for the detection, monitoring and quantification of gas bubbles. The monitoring system could be deployed on the seafloor for long-term monitoring or could be carried onboard movable platforms such as ROV’s (Remote Operated Vehicles) or AUV’s (Autonomous Underwater Vehicles) for systematic surveys of the sub-seabed storage areas

[The "Pozzo del Merro" drowned sinkhole: 20 years of exploration and study]

[In Italian

Panarea natural-lab: eight years of underwater research

The volcanic island of Panarea is characterized by the presence of continuous emission of volcanic gases from the seafloor. In November 2002 the system increased its flow of some order of magnitude and since then a steady release of gas is present generating bubble plumes that, in the shallowest points, reach the sea surface. Due to the environmental conditions, the area close to the shore and shallow water can be utilized as a “natural lab” to study the effect of high levels of CO2on the marine realm by surface techniques and directly by means of SCUBA diving. Since 2002, over one hundred hours of diving have been utilized to collect samples of fluids and sediments and to study the biota. After a first phase of volcanic surveillance, the island is more recently studied as a “natural analogue” for the development of reliable monitoring techniques for potential seepage from sub-seabed carbon storage sites. Hereby we present a synthesis of eight years of research in the area

Field study and laboratory experiments of bubble plumes in shallow seas as analogues of sub-seabed CO2 leakages

To understand the effects of increased levels of CO2 on the marine realm, it is possible to study areas where, for natural reasons, there are emissions of CO2 from the seabed. One of these areas is located east of Panarea Island (Aeolian Islands - Southern Tyrrhenian Sea - Italy). Here, the volcanic activity that characterizes the Aeolian archipelago causes a continuous release of CO2 (up to 98% of the total gas) from several vents on the seafloor in shallow water. This area was studied by means of surface techniques and direct SCUBA diving surveys; the data presented refers to a field campaign performed in 2008. To collect the necessary data, some dedicated sampling and measuring techniques were developed for use in an underwater environment. The chemistry of the fluids and their influence on the water body was determined via logs and transects in the field and by gas-chromatographic and liquid-chromatographic laboratory analysis. The flux from some of the main gas vents was also measured directly underwater. Furthermore, some laboratory experiments in a two-layer stratified fluid were conducted to understand the main features of the physical interaction of a gas plume with the surrounding environment. Both field and laboratory experiments show that there is a development of a pseudo-convective cell around the rising plume with the formation of vortices that act as a physical barrier thus reducing the interaction between the plume and the surrounding water. (C) 2010 Elsevier Ltd. All rights reserved